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[QUOTE=mariammal;184109][B]Document Described : [/B]Chemistry Question Paper, Tamil Nadu Question Paper

[B]Model Question Paper
PART - III
CHEMISTRY  [/B]
[B]Time Allowed [/B]:3 Hours Max Marks: 150

[B]Note  [/B]: i. Answer all the questions from Part -1
ii. Answer any fifteen questions from Part - II
iii. Answer any seven questions from Part-III covering all sections and choosing atleast two from each section.
iv. Answer question number 70 and any three from the remaining questions in Part IV.
v. Draw diagrams and write equations wherever necessary.

[URL]http://dge.tn.gov.in/schoolsyllabus/[/URL]

[B]English Medium Chemistry Question Paper Link :[/B]
[URL]http://dge.tn.gov.in/schoolsyllabus/blueprint/class12CHEQ.pdf[/URL]

[B]Tamil Medium Chemistry Question Paper Link :
[/B][URL]http://dge.tn.gov.in/schoolsyllabus/blueprint/class12CHTQ.pdf[/URL]

[B] PART – I[/B]
[B]Note  [/B]: Answer all the questions (30 x 1 = 30)
Choose and write the correct answer
1. En = -313.6/n2, If the value of Ei = -34.84 to which value ‘ n’ corresponds to
(a) 4 (b) 3 (c) 2 (d) 1
2. The bond order of nitrogen molecule is
(a) 2.5 (b) 3 (c) 2 (d) 4
3. Noble gases have _____ electron affinity
(a) High (b) Low (c) Zero (d) Very low
4. The shape of XeF4 is
(a) Tetrahedral (b) Octahedral
(c) Square planar (d) Pyramidal
5. Copper is extracted from
(a) Cuprite (b) Copper glance
(c) Malachite (d) Copper Pyrites
6. Silver salt used in photography is
(a) AgCl (b) AgNO3 (c) AgF (d) AgBr
7. The most common oxidation state of Lanthanides is
(a) +2 (b) +1 (c) +3 (d) +4
9. The geometry of [Ni(CN)4]2- is
(a) Tetrahedral (b) Square Planar (c) Triangular (d) Octahedral
10. Which of the following is used as neutron absorber in nuclear reactors?
(a) Water (b) Deuterium (c) Uranium (d) Cadmium
11. The number of chloride ions present per unit of CsCl
(a) 6 (b) 8 (c) 1 (d) 4
12. In an adiabatic process which of the following is correct?
(a), q=w (b) q=0 (c) DE=q (d) PDV=0
13. When a liquid boils, there is
(a) an increase in entropy (b) a decrease in entropy
(c) an increase in heat of vapourisation
(d) an increase in free energy
14. State of Chemical equilibrium is
(a) Dynamic (b) Stationary (c) Both a&b (d) None
17. Oil soluble dye is mixed with emulsion and emulson remains colorless then, the emulsion is
(a) O/W (b) W/O (c) O/O (d) W / W
18. Colloids are purified by
(a) precipitation (b) Coagulation (c) Dialysis (d) Filtration
21. The reaction of Lucas reagent is fast with
(a) ethanol (b) methanol (c) 2-propanol (d) 2-methyl 2-propanol
22. An organic compound C4H10O when heated with excess HI gives only one type of alkyl iodide. The Compound is
(a) diethylether (b) methyl n-propylether
(c) methyl iso propyl ether (d) n-butyl alcohol
23. When ether is exposed to air for sometime an explosive substance produced is
(a) Peroxide (b) Oxide (c) TNT (d) Superoxide
24. The compound that does not undergo Cannizzaro reaction is
(a) Formaldehyde (b) Acetaldehyde
(c) Benzaldehyde (d) Trimethyl Acetaldehyde
25 . Which of the following is least acidic?
(a) C2H5OH (b) CH3COOH (c) C6H5OH (d) ClCH2COOH
26. Nitration of nitrobenzene results in
(a) O-dinitro benzene (b) 1,3,5-trinitro benzene
(c) p-dinitrobenzene (d) m-dinitrobenzene
27. Primary amine acts as
(a) Electrophile (b) Lewis base (c) Lewis acid (d) Free radical
28. Which of the following will not undergo diazotisation?
(a) m-toluidine (b) aniline (c) p-amino phenol (d) benzylamine
29. Important constituent of cell wall is
(a) Lipid (b) Cellulose (c) Protein (d) Vitamin
30. The most abundant carbohydrate is
(a) glucose (b) fructose (c) starch (d) cellulose

[B]PART-II  [/B]:
[B]Note  [/B]: (15X3 = 45)
(i) Answer any 15 questions.
[B](ii) Answer in one or two sentences  [/B]:
31. State Heisenberg’s uncertainity principle.
32. Mention the disadvantage of Pauling Scale.
33. What is plumbo solvency.
34. Write the uses of Neon.
35. Why transition elements form complexes?
36. What is the action of heat on copper sulphate crystals?
40. State Lechatlier’s principle.
41. Define half life period.
42. What are simple and complex reactions?
43. Why colloidal system of gas in gas does not exist?
44. State Faraday’ s first law.
45. Distinguish enantiomers and diastereomers.
46. How is phenolphthalein prepared?
47. Explain the synthesis of glycerol from propylene.
48. Formaldehyde and benzaldehyde give Cannizzaro reaction but acetaldehyde does not account for this?
49. Formic acid reduces Tollen’s reagent, but acetic acid does not. Give reason.
50. An organic compound (A) having molecular formula C2H7N is treated with nitrous acid to give (B) of molecular formula C2H6O which on mild oxidation gives compound (C) of molecular formula C2H4O which answers Tollens reagent test. Identify A, B, C.
51. Ilustrate with suitables the term ‘Anaesthetics’.

[B]PART - III  [/B]:
[B]Note  [/B]: (7 x 5 = 35)
(i) Answer any Seven questions choosing at least two questions from each section.
[B]Section - A  [/B]:
52. The approximate mass of an electron is 10-27g. Calculate the uncertainty in its velocity. If the the uncertainity in its position were of the order of 10-11m.
53. Explain the extraction of silver from its chief ore.
54. What is Ianthanide contraction? Discuss its consequences.
55. Explain Co-ordination isomerism and ionisation isomerism with suitable examples.

[B]Section - B  [/B]:
56. In the thermal decomposition of N2O at 764°C, the time required to decompose half of the reactant was
263 seconds, when the initial pressure was 290 mm of Hg and 212 seconds at an initial pressure of 360 mm of Hg. What is the order of this reaction?
57. State the various statements of second law of Thermodynamics.
58. Derive the integrated Van’t Hoff equation for an equilibrium reaction.
59. Derive Nernst equation.

[B]Section - C  [/B]:
60. Distinguish between aromatic and aliphalic ethers.
61. Write notes on
i) Perkin’s reaction and
ii) Knoevenagal reaction
62. Discuss the mechanism of bromination of salicyclic acid.
63. Explain briefly on characteristics of rocket propellants.

[B]PART-IV  [/B]: (4 x 10 = 40)
[B]Note  [/B]: Answer question number 70 and any three from the remaining questions.
64. (a) Write notes on Pauling’s and Mulliken’s Scale of Electronegativity. [5]
(b) Give an account of the structure of ortho and cyclic silicates. [5]
65. (a) Explain Werners theory of coordination compounds. [5]
(b) Explain the uses of radioactive isotopes with examples. [5]
66. (a) Write notes on any two point defects in Crystals [5]
(b) Write notes on (i) Ultrafiltration and (ii) Helmholtz double layer [5]
67. (a) Derive Henderson Equation. [5]
(b) Write notes on single electrode potential. [5]
69. (a) How can the following conversions be effected? [5]
i. Nitrobenzene to anisole
ii. Chlorobenzene to phenyl hydrazine
iii. Aniline to Benzoic acid
(b) Mention the biological functions of nucleic acids [5]
70. (a) An organic compound A (C7H6O2) reacts with NH2OH forming a crystalline compound. On warming with NaOH it forms two compounds B and C. ‘B’ is neither soluble in NaOH nor in HCl but can be oxidised to A. The compound ‘C on treatment with Con. HCl forms acid ‘D’ which on treating with soda lime gives ‘phenol’. Identify A to D. [5]
(b) Chief ore of chromium (A) on roasting with Sodium carbonate gives compound (B) and (C). B on acidification gave compound (D) which on treatment with KCl gave compound (E). Identify the compounds
A, B,C,D and E. Explain with proper chemical reactions. [5]
(OR)
(c) An organic compound A (C6H6O) gives maximum of two isomers B and C when an alkaline solution of ‘A’ is refluxed with chloroform at 333K. ‘B’ on oxidation gives an acid D. The acid ‘D’ is also obtained by treating sodium salt of A with CO2 under pressure. Identify the compounds A, B, C and D and explain with proper chemcial reactions. [5]
(d) Calculate the pH of O.IM CH3COOH Solution Disassociation constant of acetic acid is 1.8 x 10-5M. [5][/QUOTE]

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